临汾市树叶磁性的时空变化特征及其对大气重金属污染的指示   总被引：5，自引：0，他引：5       下载免费PDF全文

曹丽婉  胡守云  Appel Erwin  师尚礼  尹刚 《地球物理学报》2016,59(5):1729-1742

粉煤灰经工厂废气排放进入大气,对人类健康和生态系统都造成了无法弥补的破坏.本文选取具有高空间分辨率优势的树叶作为收集粉煤灰的载体,对临汾市大气中可吸入颗粒物进行磁学参数和重金属含量监测.结果表明,磁化率最大值出现在工厂污染源附近,磁化率空间分布呈现随污染源距离增加而降低的趋势.工业区收集到的磁性颗粒以低矫顽力、粗粒度的磁铁矿为主.夏季磁性矿物来源单一,主要为人为影响.冬季大气中悬浮的磁性颗粒有部分来自于西北风/北风的自然尘降.同一采样点磁化率随时间变化特征表明,树叶的磁学性质可以灵敏和有效地反映较短时期内大气污染的现状.统计分析表明磁化率和重金属元素(铁,铬,镍,铜,铅,钴)之间存在显著相关性.污染负荷指数用于评估研究区域内重金属各元素综合污染的程度.结果显示,在废弃的旧工业区附近无大气污染指示,但在运营中的工厂集中的地区,大气均受到严重污染.污染负荷指数与表征磁性矿物含量的磁化率呈相关性(r2=0.66),因此树叶的磁性参数可以作为大气重金属污染的替代指标.  相似文献   

大气污染对北京冬季城市和郊区辐射收支影响的观测分析   总被引：3，自引：1，他引：2       下载免费PDF全文

王昕然  苗世光  窦军霞  董璠  王京丽 《地球物理学报》2016,59(11):3996-4006

近年来城市化和大气污染对辐射收支的影响日益显著.本研究利用2013—2014年中国科学院大气物理研究所325m铁塔、南郊观象台、密云气象塔、上甸子区域大气本底站四个观测站点的辐射及自动站气象要素数据,采用南郊观象台的能见度资料将观测数据分为清洁天和污染天,并进行类比分析,以1月份为例,研究了北京地区大气污染和城郊差异对辐射收支的影响.结果表明:(1)从月平均值来看,各站污染天入射短波辐射均小于清洁天,衰减最大可达55.8W·m~(-2),直接辐射亦然,衰减最大可达161.1W·m~(-2),散射辐射相反,增加最大值为72.2W·m~(-2);长波辐射污染天大于清洁天,向下向上长波辐射增加最大值分别为85.0 W·m~2和70.0 W·m~(-2),且长波辐射的衰减与污染物浓度和大气温度相关;净辐射白天污染天小于清洁天,夜间相反.(2)从各站的对比可知,大气污染对入射短波辐射的衰减,南部郊区(13.2%)大于北部城区(7.4%),与北京地区"南北两重天"的污染物分布特征一致;且污染物对长短波辐射的影响呈现了从城区到郊区衰减率依次减小的现象.本研究为大气污染与气象条件的相互作用研究提供了观测基础.  相似文献   

Improving estimates of oil pollution to the sea from land-based sources     

Laurel Saito  Michael R. Rosen 《Marine pollution bulletin》2010,60(7):990-997

This paper presents improvements to calculation methods used in the National Research Council’s (NRC) Oil in the Sea reports from 2003 and 1985 to estimate land-based contributions of petroleum hydrocarbons to the sea from North America. Using procedures similar to the 2003 report, but with more robust methods for handling non-detections, estimated land-based contributions for 1977 and 2000 were over 50% lower than the best 1996 estimate in the NRC report. The largest loads were from the northeastern United States and the Gulf of Mexico region for both the 2003 report and updated calculations. Calculations involved many sources of uncertainty, including lack of available data, variable methods of measuring and reporting data, and variable methods of reporting values below detection limits. This updated analysis of land-based loads of petroleum hydrocarbons to the sea highlights the continued need for more monitoring and research on inputs, fates and effects of these sources.  相似文献   

Polycyclic aromatic hydrocarbons in water,mussels (Brachidontes sp., Tagelus sp.) and fish (Odontesthes sp.) from Bahía Blanca Estuary,Argentina     

Andres H. Arias  Carla V. Spetter  Rubén H. Freije  Jorge E. Marcovecchio 《Estuarine, Coastal and Shelf Science》2009

Polycyclic aromatic hydrocarbons (PAHs), one of the major groups of anthropogenic environmental pollutants, were firstly identified and measured in coastal waters, native mussels and fish of an industrialized South American estuary.  相似文献   

Impact of septic tank systems on local groundwater quality and water supply in the Pearl River Delta,China: case study     

Yintao Lu  Changyuan Tang  Jianyao Chen  Yasuo Sakura 《水文研究》2008,22(3):443-450

Located at southern coast of China, the Pearl River Delta (PRD) is facing serious water problems in both quantity and quality after its rapid urbanization in the last decade. Most remarkably, the local groundwater, that was used to be the source of drinking water before the urbanization was polluted due to poor management of the septic tanks. In order to study the effects of suburban development on local groundwater flow and water quality in the PRD region, Fengcun of Guangzhou has been chosen as the study area. In Fengcun, drinking water was groundwater before the 1990s, but now piped reservoir water is used by each family because the groundwater has been polluted. This study clarifies the source and process of the groundwater pollution from septic tanks using isotopic and geochemical characteristics, especially nitrate (NO₃^?) concentrations. Water samples were collected from the wells and ponds in Fengcun in March and July 2005 and in July 2006. Based on the pe–pH diagram, NO₃^? and ammonium of groundwater are from the effect of human activities, rather than from nitrification and ammonification of N₂. NO₃^? pollution of groundwater is from point sources, and NO₃^? concentrations decrease from northeast to southwest. Groundwater is polluted rapidly by the leakage of septic tanks. NO₃^? concentrations of pollution sources were lower than 20 mg l^?1 in March 2005, but had increased to about 120 mg l^?1 in July 2006. This implies that groundwater protection should be strengthened in rural areas of the PRD. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

TOPCAT‐NP: a minimum information requirement model for simulation of flow and nutrient transport from agricultural systems     

P. F. Quinn  C. J. M. Hewett  N. D. K. Dayawansa 《水文研究》2008,22(14):2565-2580

Future catchment planning requires a good understanding of the impacts of land use and management, especially with regard to nutrient pollution. A range of readily usable tools, including models, can play a critical role in underpinning robust decision‐making. Modelling tools must articulate our process understanding, make links to a range of catchment characteristics and scales and have the capability to reflect future land‐use management changes. Hence, the model application can play an important part in giving confidence to policy makers that positive outcomes will arise from any proposed land‐use changes. Here, a minimum information requirement (MIR) modelling approach is presented that creates simple, parsimonious models based on more complex physically based models, which makes the model more appropriate to catchment‐scale applications. This paper shows three separate MIR models that represent flow, nitrate losses and phosphorus losses. These models are integrated into a single catchment model (TOPCAT‐NP), which has the advantage that certain model components (such as soil type and flow paths) are shared by all three MIR models. The integrated model can simulate a number of land‐use activities that relate to typical land‐use management practices. The modelling process also gives insight into the seasonal and event nature of nutrient losses exhibited at a range of catchment scales. Three case studies are presented to reflect the range of applicability of the model. The three studies show how different runoff and nutrient loss regimes in different soil/geological and global locations can be simulated using the same model. The first case study models intense agricultural land uses in Denmark (Gjern, 114 km²), the second is an intense agricultural area dominated by high superphosphate applications in Australia (Ellen Brook, 66 km²) and the third is a small research‐scale catchment in the UK (Bollington Hall, 2 km²). Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Granulometric selectivity in Liza ramado and potential contamination resulting from heavy metal load in feeding areas     

Sílvia Pedro  Vera Canastreiro  Isabel Caçador  Eduarda Pereira  Armando C. Duarte  Pedro Raposo de Almeida 《Estuarine, Coastal and Shelf Science》2008

The stomach contents of thin-lipped grey mullets Liza ramado were analysed in terms of granulometric composition and compared to the sediment of potential feeding areas in the Tagus estuary. Total organic matter (TOM) content and heavy metal content were determined in the surface sediment of three areas and eight trace elements were quantified: Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn. The three sampled areas did not differ in TOM; and the heavy metal content was below Effects Range-Low level for most elements. The mean observed concentrations were present in the following sequence: Zn > Pb > Cr > Cu ≈ Ni > Co > Cd > Hg. Stomach contents granulometric composition provided information about the feeding selectivity of the mullets. Sediment fractions with particle size between 20 and 50 μm are preferred, independently of the fishes' length. Smaller standard length (SL) fishes have a higher positive selection of fine grained sediments than those with a larger SL. Finer fractions usually have higher concentration of heavy metals, which makes younger specimens of the thin-lipped grey mullet potentially more exposed to heavy metal load in the estuary. Metal concentration was not independent from the sampling point, presenting higher values near the margins and the estuary tidal drainage system. This means that during the first period of each tidal cycle, the mullets will feed first on the most contaminated areas, as a consequence of their movement following the rising tide to feed on previously exposed areas.  相似文献   

Microbial diversity in polluted harbor sediments II: Sulfate-reducing bacterial community assessment using terminal restriction fragment length polymorphism and clone library of dsrAB gene     

Wen Zhang  Lin-sheng Song  Jang-Seu Ki  Chun-Kwan Lau  Xiang-Dong Li  Pei-Yuan Qian 《Estuarine, Coastal and Shelf Science》2008

Sulfate-reducing bacteria (SRB) are important regulators of a variety of processes in coastal marine sediments regarding organic matter turnover, biodegradation of pollutants, and sulfur and carbon cycles. Yet their community compositions have not been investigated in polluted harbor sediments. This study described the diversity and spatial variation of SRB communities in surface sediments in Victoria Harbor, Hong Kong. The spatial variation of SRB communities was described by terminal restriction fragment length polymorphism (T-RFLP). The results showed that the most diversified terminal restriction fragments were found at polluted sites. In addition, cluster analysis indicated that although the SRB communities were different at the two polluted sites, they were still more similar to each other than to the two more distant reference sites. Based on a dsrAB clone library constructed at a polluted site, diversified SRB were found, represented by 30 Operational Taxonomic Units (OTUs). Upon comparisons among the SRB sequences detected from this study and those in the GenBank, five clades of SRB were found. Three clades belonged to the known families Desulfobacteraceae, Desulfobulbaceae, and Syntrophobacteriaceae. The majority of sequenced clones, which distantly related to sequences in the GenBank, constituted the remaining two unclassified groups, suggesting unique SRB members related to the polluted harbor environment. Statistical analyses indicated that estimated SRB richness correlated with environment factors such as sulfur content, acid volatile sulfate, and redox potential.  相似文献   

Agricultural land use and hydrology affect variability of shallow groundwater nitrate concentration in South Florida     

A. Ritter  R. Muñoz‐Carpena  D. D. Bosch  B. Schaffer  T. L. Potter 《水文研究》2007,21(18):2464-2473

South Florida's Miami‐Dade agricultural area is located between two protected natural areas, the Biscayne and Everglades National Parks, subject to the costliest environmental restoration project in history. Agriculture, an important economic activity in the region, competes for land and water resources with the restoration efforts and Miami's urban sprawl. The objective of this study, understanding water quality interactions between agricultural land use and the shallow regional aquifer, is critical to the reduction of agriculture's potentially negative impacts. A study was conducted in a 4‐ha square field containing 0·9 ha of corn surrounded by fallow land. The crop rows were oriented NW–SE along the dominant groundwater flow in the area. A network of 18 monitoring wells was distributed across the field. Shallow groundwater nitrate–nitrogen concentration [N‐NO₃^?] was analyzed on samples collected from the wells biweekly for 3 years. Detailed hydrological (water table elevation [WTE] at each well, groundwater flow direction [GwFD], rainfall) and crop (irrigation, fertilization, calendar) data were also recorded in situ. Flow direction is locally affected by seasonal regional drainage through canal management exercised by the local water authority. The data set was analyzed by dynamic factor analysis (DFA), a specialized time series statistical technique only recently applied in hydrology. In a first step, the observed nitrate variation was successfully described by five common trends representing the unexplained variability. By including the measured hydrological series as explanatory variables the trends were reduced to only three. The analysis yields a quantification of the effects of hydrological factors over local groundwater nitrate concentration. Furthermore, a spatial structure across the field, matching land use, was found in the five remaining common trends whereby the groundwater [N‐NO₃^?] in wells within the corn rows could be generally separated from those in fallow land NW and SE of the crop strip. Fertilization, masked by soil/water/plant‐delayed processes, had no discernible effect on groundwater nitrate levels. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

灵山岛空气微生物含量的测定   总被引：2，自引：0，他引：2  

孙丕喜  陈皓文  黄秀兰 《海岸工程》2008,27(4):37-41

用平皿自然沉降法测定灵山岛空气微生物及肠道致病菌，结果表明该岛处于空气微生物中-轻度污染状态，以轻度污染为主，其中细菌为主要成分，也舍少量肠病菌，空气微生物显出某种时空变化势态，且与气温、人群活动等因素相关，推测谈岛脆弱的生态环境易被外界干扰，应引起关注。  相似文献